Journal of Liaoning Petrochemical University
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Removal of Basic Nitrogen Compounds From Shale Oil
ZHANG Zhe-ming,ZHAO De-zhi,ZHANG Han-ming,ZHU Yun-yan, ZHENG Xiao-ming, ZHAO Bo
Abstract558)      PDF (262KB)(293)      
 
The basic nitrogen-compounds were removed with complexation by denitrification reagent form the Fushun shale oil. The effect of reaction temperature, reaction time, volume ratio of agent to oil, complexing agent amount and settling time on the denitrification ratio and yield were investigated. The optimum operating conditions are as follows: The temperature 55~60 ℃, reaction time 5 min, volume ratio agent and oil 0.07, auxiliary usage 1∶0.5~1∶1, motionless time 35 min. Under these conditions, the denitrification ratio and oil yield can reach 95.36% and 91.25%, respectively. The results show that mixed solvent could be used in denitrification with high efficiency, pH of the shale oil dealed with reagent B is neutral.
2011, 31 (3): 24-27. DOI: 10.3696/j.issn.1672-6952.2011.03.007
Product Yield Model of Strengthened Delayed Coking
JIU Qiao-na, ZHAO De-zhi, ZHANG Lei,ZHU Yun-yan,ZHU Ying-di
Abstract458)      PDF (170KB)(295)      
 
According to the action mechanism of delayed coking, the nature of raw materials and product yield were simulated by Matlab through the collected data. The results indicate that coke yield, liquid yield, and gas yield have a good multi-linear relationship with strengthened delayed coking feedstock density, residual carbon, molar ratio of hydrogen to carbon, and four crude oil components (resin and asphaltene, saturated hydrocarbons, and aromatic).
2010, 30 (3): 32-35. DOI: 10.3696/j.issn.1672-6952.2010.03.009